Synthesis of the New Type of Water-Soluble Ligand N,N-Bis- (diphenylphosphinomethyl)-2-aminoethylphosphonic Acid (Ph2PCH2)2NCH2CH2PO3H2 and Its Sodium Salt

نویسندگان

  • Xuebing Ma
  • Xiangkai Fu
  • Longqin Li
  • Jingrong Chen
چکیده

The novel water-soluble ligand, N,N-bis(diphenylphosphinomethyl)-2-aminoethylphosphonic acid, (Ph2PCH2)2NCH2CH2PO3H2, had been synthesized in quantitative yield by reaction of 2-aminoethylphosphonic acid with bis(hydroxymethyl)diphenylphosphonium chloride in water. Its monoand disodium salts, which can be used as water-soluble ligands for transition metal complex catalysts, were also easily prepared under mild conditions.

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تاریخ انتشار 2001